photomultiplier
Photomultiplier tubes (photomultipliers or PMTs for short), members of the class of vacuum tubes, and more specifically phototubes, are extremely sensitive detectors of light in the ultraviolet, visible and near infrared. These detectors multiply the signal produced by incident light by as much as 108 (i.e., 160 dB), enabling (for example) single photons to be individually detected when the incident flux of light is very low. The combination of high gain, low noise, high frequency response and large area of collection has earned photomultipliers an essential place in in nuclear and particle physics, astronomy, medical diagnostics including blood tests, medical imaging and motion picture film scanning (telecine). Semiconductor devices, particularly avalanche photodiodes, compete with them, but photomultipliers are uniquely well-suited for applications requiring low-noise, high-sensitivity detection of light which is imperfectly collimated. While photomultipliers are extraordinarily sensitive and moderately efficient, research is still underway to create a photon-counting light detection device that is >>99% efficient; such a detector is of interest for applications related to quantum information and quantum cryptography. Elements of photomultiplier technology, integrated differently, are the basis of night vision devices.
History
The photomultiplier, invented in 1936, is rooted in the science of the photoelectric effect, and that of secondary emission - i.e., the ability of electrons in a vacuum tube to, by striking an electrode, cause the emission of additional electrons.
Although the photoelectric effect is perhaps most associated with Einstein who educed the fundamental principle of quantization (i.e., the basis of quantum mechanics) for which he received the 1921 Nobel Prize, the phenomenon had been known earlier without understanding the quantum mechanical proportionality between optical frequency and photon energy.
The phenomenon of secondary emission was first limited to purely electronic inventions (i.e., those lacking photosensitivity). In 1902, Austin and Starke reported[H. Bruining, Physics and applications of secondary electron emission, (McGraw-Hill Book Co., Inc.; 1954).] that the metal surfaces impacted by electron beams emitted a larger number of electrons than were incident. But the use of secondary emission as a means for signal amplification was not proposed until after World War I, by Slepian in a 1919 Westinghouse patent.[J. Slepian, Westinghouse Electric, "Hot Cathode Tube," U.S. Patent 1, 450, 265, April 3, 1923 (Filed 1919)]
Finally, 16 years later, the phenomenon of photoemission (the photoelectric effect) was combined with secondary emission to create the photomultiplier. In 1935, Iams and Salzberg[H. E. Iams and B. Salzberg, “The secondary emission phototube,” Proc. IRE, Vol. 23, pp. 55-64 (1935).] of RCA reported on a single-stage photomultiplier. The device consisted of a semicylindrical photocathode, a secondary emitter mounted on the axis, and a collector grid surrounding the secondary emitter. The tube had a gain of about eight.
In 1936, Zworykin, Morton, and Malter, of RCA, first reported a tube that amplified the current of photoemitted electrons in multiple stages — what was later called the photomultiplier.[V.K. Zworykin, G.A. Morton, and L.Malter, "The secondary-emission multiplier-a new electronic device,” Proc. IRE, Vol. 24, pp. 351-375 (1936).]
The first experimental photomultipliers used a Ag-O-Cs photocathode having a typical peak quantum efficiency
of 0.4% at 800 nm.
Also in 1936, a much improved photocathode, Cs3Sb, was reported by Gorlich[P. Gorlich, “Uber zusammengesetzte, durchsichtige Photokathoden,” 2. Physik, Vol. 101, p. 335 (1936).]. The Cs3Sb photocathode had a dramatically improved quantum efficiency of 12% at 400 nm and was used in the first commercially successful photomultipliers manufactured by RCA, the 931-type, both as a photocathode and as a secondary-emitting material for the dynodes. Different photocathodes provided differing spectral responses.
Spectral Response of Photocathodes
In the early 1940’s, the JEDEC (Joint Electron Devices Engineering Council), an industry committee on photosensitive devices, developed a system of designating spectral responses.["Relative spectral response data for]
photosensitive devices (“S” curves)," JEDEC Publication No. 50, Electronic Industries Association, Engineering Department, 2001 I Street, N.W., Washington, D.C. 20006 (1964) The philosophy included the idea that the product user need only be concerned about the response of the device, not by how it might be fabricated. S-numbers were registered from S-l through S-40. S-11, for example, relied on the Cs3Sb photocathode. S-25 used a so-called "multialkali" photocathode Na2KSb:Cs that provided extended response in the red portion of the visible spectrum. These terms are still used today.
At wavelengths longer than approximately 1 µm no suitable photoemissive surfaces have yet been reported. Consequently photomultipliers are not available at such wavelengths.
Role of RCA
For decades, by far the most important work developing and refining photomultipliers was performed, and the components themselves commercialized, by RCA. The company compiled and published an authoritative and very widely used Photomultiplier Handbook. RCA made printed copies available gratis upon request. The volume, which continues to be made available on-line at no cost by the successors to RCA (see below), is considered an essential reference.
Following a corporate break-up in the late 1980s involving the acquisition of RCA by General Electric and disposition of the divisions of RCA to numerous third-parties, RCA's photomultiplier business became an independent company.
Lancaster, Pennsylvania facility
The Lancaster, Pennsylvania facility was opened by the U.S. Navy in 1942 and operated by RCA for the manufacture of radio and microwave tubes. Following the Allied victory, it was acquired by RCA. RCA Lancaster, as it became known, was the base for development and production of commercial television products. In subsequent years other products were added. These included image tubes, photomultiplier tubes, motion-sensing light control switches, and closed circuit video systems.
Transition to Burle Industries
Burle Industries, as the successor to the RCA Corporation, has carried the RCA photomultiplier business forward since 1986 based in the Lancaster, PA facility. The 1986 acquisition of RCA by General Electric resulted in the divestiture of the RCA Lancaster New Products Division. Hence, 45 years after being founded by the U.S. Navy, its management team, led by Erich Burlefinger, purchased the Division and in 1987 founded Burle Industries.
The RCA Photomultipler Handbook, along with another famous RCA reference work, is available on the Burle website.[PhotoMultiplier Hand-Book]
Then, following 18 years as an independent enterprise, Burle Industries and a key subsidiary were acquired in 2005 by Photonis, a European holding company Photonis Group. Following the acquisition Photonis comprised Photonis Netherlands, Photonis France, Photonics USA, and Burle Industries. Photonis USA operates the former Galileo Corporation Scientific Detector Products Group, (Sturbridge, MA) which had been purchased by Burle in 1999, and is known for microchannel plate detector (MCP) electron multipliers (an integrated micro-vacuum tube versions of photomultipliers). MCPs are used for imaging and scientific applications including night vision devices.
Other companies
The Japanese-based company Hamamatsu Photonics has emerged since the 1960s as a leader in the photomultiplier business. Hamamatsu, as it is known, has published its own handbook available on its website in the tradition of RCA.
Structure and operating principles
Photomultipliers are constructed from a glass vacuum tube which houses a photocathode, several dynodes, and an anode. Incident photons strike the photocathode material which is present as a thin deposit on the entry window of the device, with electrons being produced as a consequence of the photoelectric effect. These electrons are directed by the focusing electrode towards the electron multiplier, where electrons are multiplied by the process of secondary emission.
The electron multiplier consists of a number of electrodes, called dynodes. Each dynode is held at a more positive voltage than the previous one. The electrons leave the photocathode, having the energy of the incoming photon (minus the work function of the photocathode). As they move towards the first dynode they are accelerated by the electric field and arrive with much greater energy. On striking the first dynode, more low energy electrons are emitted and these, in turn, are accelerated toward the second dynode. The geometry of the dynode chain is such that a cascade occurs with an ever-increasing number of electrons being produced at each stage. Finally the anode is reached where the accumulation of charge results in a sharp current pulse indicating the arrival of a photon at the photocathode.
Usage considerations
Photomultiplier tubes typically utilize 1000 to 2000 volts to accelerate electrons within the chain of dynodes. The most negative voltage is connected to the cathode, and the most positive voltage is connected to the anode. Negative high voltage supplies (with positive terminal grounded) are preferred, because this configuration enables the photocurrent to be measured at the low voltage side of the circuit for amplification by subsequent electronic circuits operating at low voltage. Voltages are distributed to the dynodes by a resistive voltage divider, though variations such as active designs (with transistors or diodes) are possible. The divider design, which influences frequency response or rise time, can be selected to suit varying applications.
While powered, photomultipliers must be shielded from ambient light to prevent their destruction through overexcitation. If used in a location with high magnetic fields (which will curve electron paths), they are usually shielded by a layer of mu-metal.
Typical applications
Photomultipliers were the first "electric eye" devices. They were used to measure breaks in light beams.
Photomultipliers are used in conjunction with scintillators to detect nuclear and particle radiation in physics experiments.
Photomultipliers are used in the research laboratory to measure the intensity and spectrum of light emitting materials such as compound semiconductors and quantum dots.
Photomultipliers are used in numerous medical equipment designs. For example, blood analyzers used by clinical medical laboratories utilize photomultipliers to determine the relative concentration of various components of blood vials drawn in doctors' offices, in combination with optical filters and incandescent lamps.
High sensitivity applications
After 50 years during which solid state electronic components have largely displaced the vacuum tube, the photomultiplier remains a unique and important optoelectronic component. Perhaps its most useful quality is that it acts, electronically, as a nearly perfect current source owing to the high voltage utilized in extracting the tiny currents associated with weak light signals. There is no Johnson noise associated with photomultiplier signal currents even though they are greatly amplified, e.g., by 105 (i.e., by 100 dB) or more.
Photomultiplier-amplified photocurrents can be electronically amplified by a high-input-impedance electronic amplifier (in the signal path, subsequent to the photomultiplier), thus producing appreciable voltages even for nearly infinitesimally small photon fluxes. Photomultipliers offer the best possible opportunity to exceed the Johnson noise for many configurations. The aforementioned refers to measurement of light fluxes that, while small, nonetheless amount to a continuous stream of multiple photons.
For smaller photon fluxes, the photomultiplier can be operated in photon counting or in Geiger mode (c.f., Single-Photon Avalanche Diode). In Geiger mode, the photomultiplier gain is set so high (using high voltage) that a single photo-electron (resulting from a single photon incident on the primary surface) generates a very large current at the output circuit but owing to the avalanche of current requires a reset of the photomultiplier. In either case, the photomultiplier can detect individual photons. The drawback, however, is that not every photon incident on the primary surface is counted either because of less-than-perfect efficiency of the photomultiplier or because a second photon can arrive at the photomultiplier during the "dead time" associated with a first photon and never be noticed.
Nonetheless, the ability to detect single photons striking the primary photosensitive surface itself reveals the quantization principle that Einstein put forth. Photon-counting (as it is called) reveals that light, not only being a wave, consists of discrete particles (i.e., photons).
See also
 Phototube
Geiger counter
Scintillation counter
Microchannel plate
Lucas cell
References
Bibliography
Engstrom, Ralph W., Photomultiplier Handbook, RCA (1980).
Photomultiplier Tubes: Basics and Applications (Second Edition), Hamamatsu Photonics, Hamamatsu City, Japan, (1999).
Flyckt, S.O. and Marmonier, C., Photomultiplier Tubes: Principles and Applications, Philips Photonics, Brive, France (2002).
External links
Electron Multiplier Simulation of electron multiplier tube
Molecular expressions A java simulation and tutorial on photomultiplier tubes
Photomultiplier Tubes Basics and Applications from Hamamatsu Photonics
Photomultiplier Handbook (4MB PDF) from Burle Industries, essentially the Engstrom-RCA Handbook reprinted
Photomultiplier Technical Papers from Electron Tubes Ltd
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